ISSN 1000-3665 CN 11-2202/P

    CO2地质封存过程浅层地下水响应的研究进展与展望

    Progress and prospects of the shallow groundwater responding to CO2 geological storage

    • 摘要:
      目的 为阐明规模化CO2注入以及注入的CO2与储层咸水泄漏后对浅层地下水的潜在影响,以支撑CO2地质封存项目开展泄漏风险防控与浅层地下水保护。
      方法 文章采用文献分析法,系统总结了CO2地质封存规模化注入与储层流体泄漏迁移对浅层地下水流场和水质的影响研究进展。
      结果 结果表明:(1)规模化CO2注入引起的储层压力集聚和压力扰动传导至浅部含水层,会引发浅层地下水水位抬升、压力增加、蒸散发量增大等现象;(2)当CO2或储层咸水沿泄漏通道迁移至浅部含水层时,将导致浅层地下水pH与ORP降低、碱度-电导率等参数升高、Ca-Mg-K等主要离子浓度升高、有毒微量金属释放迁移、微生物群落生物多样性与代谢多样性改变等复杂生物地球化学过程,变化程度受CO2或储层水泄漏强度、浅部含水层水文地质条件等多个因素影响;(3)吸附与解吸、溶解与沉淀、氧化还原反应是CO2侵入后地下水水质变化的主要反应机制。
      结论 浅层地下水不仅是CO2地质封存工程泄漏的风险受体,亦是开展封存安全性与有效性评估的信息载体,应重视规模化CO2地质封存工程浅层地下水影响与监测研究,在避免发生环境影响事件的同时,为封存有效性论证提供支撑。

       

      Abstract:
      Objective To clarify the potential impacts of large-scale CO2 injection and the leakage of injected CO2 along with reservoir brine on shallow groundwater, thereby supporting risk prevention and control for leakage in CO2 geological storage projects and the protection of shallow groundwater.
      Methods This paper employs the literature analysis method to systematically summarize research progress on the impacts of large-scale CO2 geological storage injection and reservoir fluid leakage migration on shallow groundwater flow fields and water quality.
      Results Large-scale CO2 injection leads to reservoir pressure accumulation and pressure disturbance transmission into shallow aquifers, resulting in phenomena such as rising groundwater levels, increased pressure, and enhanced evapotranspiration. The leakage of CO2 or reservoir brine to shallow aquifers can lead to a decrease in pH and ORP, an increase in parameters such as alkalinity and electrical conductivity, elevated concentrations of major ions like Ca-Mg-K, release and migration of toxic trace metals, and alterations in the biodiversity and metabolic diversity of microbial communities. These complex biogeochemical processes are influenced by factors such as the intensity of CO2 or reservoir brine leakage and the hydrogeological conditions of the shallow aquifer. Adsorption and desorption, dissolution and precipitation, and redox reactions are the primary mechanisms governing changes in groundwater quality following CO2 intrusion .
      Conclusions Shallow groundwater serves not only as a risk receptor for potential leakage in CO2 geological storage projects but also as an information carrier for assessing storage safety and effectiveness. Therefore, greater emphasis should be placed on researching the impacts and monitoring of shallow groundwater in large-scale CO2 geological storage projects, both to prevent environmental incidents and to provide support for verifying storage effectiveness .

       

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