ISSN 1000-3665 CN 11-2202/P

    雄安新区牛驼镇地热田岩溶热储水文地球化学特征及演化过程研究

    Hydrogeochemical characteristics and evolution process of karst thermal reservoir in Niutuo Town geothermal field of Xiong 'an New Area

    • 摘要:
      目的 蓟县系岩溶热储是雄安新区牛驼镇地热田目前开发利用的主力储层,本研究旨在解析雄安新区牛驼镇地热田蓟县系岩溶热储中地热流体Na+、Cl富集与SO42−缺失的成因机制,定量揭示其物质来源及热储内部水-岩相互作用的动态规律。
      方法 通过采集地表水及蓟县系雾迷山组、高于庄组地热水样品共40组,综合运用水化学与同位素分析、水文地球化学反向模拟等方法,系统研究热储的水文地球化学演化过程。
      结果 研究表明:岩溶热储地热流体主要来源于大气降水补给,整体表现为高Na+、高Cl、高溶解性总固体和低SO42−的特征;大气降水入渗后,在深部循环过程中,流体经热源加热并与围岩发生充分的溶滤作用、阳离子交替吸附及脱硫酸作用,共同控制地热流体化学组成,最终形成如今的水文地球化学特征;水文地球化学模拟显示,从补给区(太行山区)向研究区运移路径上,矿物反应量及反应速率显著较高,而在地热田内部径流过程中明显减小。
      结论 本研究系统揭示了蓟县系岩溶热储中水-岩相互作用的主导机制,创新性地采用水文地球化学反向模拟方法,定量揭示了各矿物溶解沉淀对水化学演化的贡献,明确了地热流体组分的来源与演化路径,为地热资源形成机理与可持续评价提供了科学依据。

       

      Abstract:
      Objective The Jixian System karst geothermal reservoir serves as the primary production reservoir in the Niutuozhen geothermal field, Xiong’an New Area, where geothermal fluids present pronounced Na+ and Cl enrichment coupled with SO42− depletion. However, the genetic mechanisms and quantitative dynamics of mineral-fluid interactions responsible for these geochemical signatures remain insufficiently characterized.
      Methods To elucidate the origin of fluid components and quantify water-rock interaction processes within the reservoir, this study analyzed 40 surface water and groundwater samples from the Jixian System’s Wumishan and Gaoyuzhuang formations. Integrating hydrochemistry, stable isotopic tracers, and hydrogeochemical inverse modeling, this study delineated the evolutionary pathways of fluid geochemistry.
      Results The results demonstrate that the geothermal fluids in the karst reservoir primarily originate from atmospheric precipitation, exhibiting high Na+, Cl, and Total Dissolved Solids (TDS) concentrations alongside low SO42− levels. After infiltration, the meteoric water undergoes deep thermal heating during long-distance migration and interacts extensively with surrounding rocks through dissolution, cation exchange, and sulfate reduction, ultimately forming the current geochemical characteristics. Hydrogeochemical modeling indicates substantial mineral reaction quantities and rates along the migration pathway from the Taihang Mountain recharge area to the study area, with these parameters decreasing significantly during internal flow processes within the geothermal field. Grounded in a detailed analysis of water-rock interaction geochemistry, this study pioneers the application of inverse hydrogeochemical modeling to quantify the relative contributions of mineral dissolution-precipitation reactions to hydrogeochemical evolution.
      Conclusions By establishing a mechanistic link between mineral phase transformations and fluid chemistry dynamics, the findings elucidate the multistage evolutionary pathways of geothermal systems while providing a novel methodological framework for geothermal resource assessment. This integrated approach not only advances understanding of subsurface fluid-rock coupling processes but also offers critical scientific support for sustainable development strategies in geothermal energy exploitation.

       

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