ISSN 1000-3665 CN 11-2202/P

    水位波动条件下轻质非水相液体迁移规律及层析电阻率响应特征

    Migration patterns of light non-aqueous liquids and chromatographic resistivity response characteristics under fluctuating water levels

    • 摘要: 本研究聚焦LNAPL地下水环境的污染问题,针对目前在复杂地下水条件下研究的不足,探究LNAPL在非饱和、恒定地下水水位及地下水水位波动3种条件下的油层、水位变化规律与电阻率响应特征,明确其迁移与水位的互馈机制,为污染场地调查与修复方案制定提供参考。采用电阻率层析成像技术开展研究,选用不同规格的有机玻璃砂箱,以粉砂作为介质、0#柴油作为LNAPL代表物,通过高密度电阻率法监测LNAPL在地下水环境中的迁移过程,监测数据经ResIPy软件进行时移反演,分别探究3种地下水条件下的相关特征。非饱和条件下,LNAPL以垂向迁移为主,最大迁移速率达5.2 cm/h,迁移稳定后介质顶部与底部电阻率最大变化量分别为317.84%和430.35%;恒定地下水水位时,LNAPL因密度小于水在油水分界面堆积形成浮油带,最大迁移速率为1.1 cm/h,稳定后介质顶部与底部电阻率最大变化量分别为285.42%和451.54%;地下水水位波动时,会促进LNAPL的横向扩散,同时改变油层厚度及高阻透镜体的存在形态。水位波动通过改变介质含水率与浮力作用影响LNAPL迁移,而LNAPL的堆积会改变砂箱内部液相压力,进而影响地下水水位。研究成果可为LNAPL污染场地的精准调查与修复方案制定提供重要参考。

       

      Abstract: Light non-aqueous phase liquid (LNAPL) contamination poses persistent challenges in groundwater systems, particularly under complex hydrodynamic conditions. However, the coupled dynamics between LNAPL migration and groundwater-level fluctuations, as well as resistivity response characteristics, remain insufficiently understood. This study investigated LNAPL migration behavior and associated resistivity responses under three representative hydrogeological conditions: unsaturated media, constant groundwater level, and fluctuating groundwater levels. Laboratory sandbox experiments were conducted using acrylic tanks filled with fine sand, with No. 0 diesel serving as a representative LNAPL. High-density electrical resistivity tomography (ERT) was employed to monitor LNAPL migration, and time-lapse inversion was performed using ResIPy software to quantify spatiotemporal resistivity variations. Under unsaturated conditions, LNAPL migrated primarily in the vertical direction, with a maximum migration rate of 5.2 cm/h. After migration stabilized, the maximum changes in resistivity between the top and bottom of the medium were 317.84% and 430.35%, respectively. Under constant groundwater levels, LNAPL accumulated at the oil-water interface to form a floating oil slick due to its lower density than water, with a maximum migration rate of 1.1 cm/h. After stabilization, the maximum changes in resistivity at the top and bottom of the medium were 285.42% and 451.54%, respectively. Fluctuations in the groundwater level promoted the lateral diffusion of LNAPL while altering the thickness of the oil layer and the morphological characteristics of the high-resistance lens. Water level fluctuations influenced LNAPL migration by altering the medium’s moisture content and buoyancy effects, while the accumulation of LNAPL altered the liquid phase pressure within the sand box, thereby affecting the groundwater level. The findings of this study provide valuable guidance for the precise investigation and development of remediation plans for sites contaminated with light non-aqueous phase liquids (LNAPLs).

       

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