利用δ~(53)Cr定量评价Cr(Ⅵ)还原程度的实验研究
An experimental study of the quantitative assessment of Cr(Ⅵ) reducibility using δ53 Cr
-
摘要: 地下水污染的"原位修复"是当今国际上净化地下水最具发展前景的新技术,但对铬污染地下水"原位修复"尚未有科学有效的评价方法。定量评价地下水中Cr(Ⅵ)的被还原程度成为保护与修复铬污染地下水的关键问题。通过室内Cr(Ⅵ)的还原实验,分析Cr(Ⅵ)在还原过程中铬稳定同位素变化规律,研究其分馏机理,探索利用铬同位素定量评价地下水中Cr(Ⅵ)还原程度的可行性。研究结果表明:Cr(Ⅵ)在被还原成Cr(Ⅲ)过程中,发生明显的同位素分馏,即反应物中53Cr逐渐富集,同时生成物中52Cr逐渐富集;分馏过程可用瑞利分馏模型描述,分馏系数α为常数0.99842。表明δ53Cr能够定量评价水体中Cr(Ⅵ)的还原程度,为评价地下水铬污染修复提供了新途径。Abstract: "In-situ remediation"of contaminated groundwater is a most prosprective technology in the world today,but there is not a scientific and effective method to estimate the technology of"In-situ remediation"of Cr-contaminated groundwater.Quantitative evaluation of Cr(Ⅵ) reducibility becomes a key problem of protection and restoration for groundwater pollution by chromium.Typical experiments of Cr(Ⅵ) reduction were conducted to analyze the changing disciplinarian of Cr(Ⅵ) stable isotopes during the r...